Chemistry - Analytical Chemistry
MCQS
A. Determining the composition of substances
B. Studying atomic structure
C. Investigating chemical reactions
D. Analyzing geological formations
The primary goal of analytical chemistry is determining the composition of substances.
A. Atomic absorption spectroscopy
B. Infrared spectroscopy
C. Nuclear magnetic resonance
D. Gas chromatography
Atomic absorption spectroscopy is commonly used for identifying and quantifying elements in a sample.
A. A technique for determining the concentration of a solution
B. A method for synthesizing new compounds
C. A process of distillation
D. A type of chromatography
Titration is a technique for determining the concentration of a solution.
A. Vapor pressure
B. Boiling point
C. Density
D. Molecular weight
Gas chromatography separates compounds based on differences in their boiling points.
A. Relating instrument response to analyte concentration
B. Identifying unknown substances
C. Quantifying atomic structure
D. Measuring reaction rates
A calibration curve is used to relate instrument response to analyte concentration.
A. Spectrophotometry
B. Mass spectrometry
C. Electrochemistry
D. NMR spectroscopy
Spectrophotometry measures the interaction of light with matter to identify and quantify substances.
A. Mass spectrometer
B. UV-Visible spectrophotometer
C. Gas chromatograph
D. NMR spectrometer
Mass spectrometry separates and identifies components based on mass-to-charge ratio.
A. Separation based on solubility
B. Separation based on vapor pressure
C. Separation based on boiling point
D. Separation based on affinity for a stationary phase
Liquid chromatography separates components based on their affinity for a stationary phase.
A. Electrochemical methods
B. Spectroscopy
C. Chromatography
D. Titration
Electrochemical methods involve passing an electric current through a solution to determine analyte concentration.
A. Reacting with the analyte to produce a product
B. Providing color to the solution
C. Acting as a solvent
D. Maintaining a constant temperature
Reagents in analytical chemistry react with the analyte to produce a measurable product.
A. Nuclear magnetic resonance (NMR)
B. Gas chromatography (GC)
C. Mass spectrometry (MS)
D. X-ray diffraction
NMR spectroscopy involves the study of the interaction between magnetic nuclei and an external magnetic field.
A. Correcting for variations in experimental conditions
B. Providing reference materials
C. Enhancing sensitivity
D. Reducing reaction rates
Internal standards in analytical chemistry help correct for variations in experimental conditions.
A. Calorimetry
B. Potentiometry
C. Polarimetry
D. Colorimetry
Calorimetry measures the amount of heat released or absorbed during a chemical reaction.
A. High-performance liquid chromatography (HPLC)
B. Gas chromatography-mass spectrometry (GC-MS)
C. X-ray fluorescence (XRF)
D. Ultraviolet-visible (UV-Vis) spectroscopy
HPLC is commonly used to separate and quantify amino acids in a sample.
A. The closeness of a measurement to the true value
B. The precision of a measurement
C. The sensitivity of an instrument
D. The linearity of a calibration curve
Accuracy in analytical chemistry refers to the closeness of a measurement to the true value.
A. Electrophoresis
B. Mass spectrometry
C. Chromatography
D. Spectrophotometry
Electrophoresis separates charged particles based on their mass-to-charge ratio in an electric field.
A. Ensuring the reliability of results
B. Selecting the most expensive instruments
C. Decreasing the precision of measurements
D. Expanding the range of experimental conditions
Quality control in analytical chemistry ensures the reliability of results through systematic checks.
A. Concentration of the analyte
B. Density of the sample
C. Temperature of the solution
D. pH of the solution
In atomic absorption spectroscopy, the amount of absorbed light is proportional to the concentration of the analyte.
A. Provides detailed information about molecular structure
B. Requires minimal sample preparation
C. Operates at low cost
D. Measures color changes in solutions
A mass spectrometer provides detailed information about the molecular structure of compounds.
A. Carries the sample through the stationary phase
B. Causes the separation of components
C. Provides stability to the column
D. Initiates the chemical reaction
The mobile phase in chromatography carries the sample through the stationary phase.
A. Precision
B. Accuracy
C. Sensitivity
D. Linearity
Precision is the measure of how closely repeated measurements agree with each other.
A. Polarimetry
B. Mass spectrometry
C. Voltammetry
D. Potentiometry
Polarimetry measures the rotation of plane-polarized light to quantify the concentration of optically active substances.
A. Inductively coupled plasma mass spectrometry (ICP-MS)
B. High-performance liquid chromatography (HPLC)
C. Fourier-transform infrared spectroscopy (FTIR)
D. X-ray photoelectron spectroscopy (XPS)
ICP-MS is commonly used for detecting and quantifying trace metals in environmental samples.
A. Records the separation pattern of components
B. Provides color to the eluent
C. Measures the absorption of light
D. Initiates the chromatographic process
The detector in chromatography records the separation pattern of components.
A. Potentiometry
B. Chromatography
C. Spectroscopy
D. Calorimetry
Potentiometry measures the electrical potential of a solution.
A. Remove interferences and enhance analyte concentration
B. Increase the volume of the sample
C. Decrease the sensitivity of the instrument
D. Speed up reaction rates
Sample preparation techniques in analytical chemistry aim to remove interferences and enhance analyte concentration.
A. Ion chromatography
B. Gas chromatography
C. Liquid chromatography
D. Thin-layer chromatography
Ion chromatography separates ions based on their mobility in a buffer solution under an electric field.
A. Atomic emission spectroscopy
B. Nuclear magnetic resonance
C. Ultraviolet-visible spectroscopy
D. Infrared spectroscopy
Atomic emission spectroscopy measures the emission of light by atoms or molecules after excitation.
A. Sensitivity
B. Specificity
C. Selectivity
D. Accuracy
Sensitivity in analytical chemistry refers to the ability to detect small changes in analyte concentration.
A. Immobilizes components, causing separation
B. Moves with the sample through the column
C. Measures the intensity of light
D. Initiates the chemical reaction
The stationary phase in chromatography immobilizes components, causing their separation during analysis.
A. Volatility
B. Refractive index
C. Density
D. Viscosity
Gas chromatography separates components based on differences in volatility.
A. Kinetic spectrophotometry
B. Fluorimetry
C. Mass spectrometry
D. Infrared spectroscopy
Kinetic spectrophotometry measures the rate of a chemical reaction by monitoring changes in absorbance or fluorescence over time.
A. To account for contamination from the environment
B. To calibrate the instrument
C. To provide a reference standard
D. To determine the precision of measurements
A blank sample in analytical chemistry helps account for contamination from the environment.
A. Headspace gas chromatography
B. Fourier-transform infrared spectroscopy
C. Liquid chromatography-mass spectrometry
D. Nuclear magnetic resonance
Headspace gas chromatography is suitable for identifying and quantifying volatile organic compounds in environmental samples.
A. To monitor the stability of the instrument
B. To validate the accuracy of results
C. To optimize reaction conditions
D. To serve as a reference standard
A control sample in analytical chemistry serves as a reference standard for comparison.
A. X-ray fluorescence (XRF)
B. X-ray diffraction (XRD)
C. X-ray photoelectron spectroscopy (XPS)
D. X-ray absorption spectroscopy
XRF measures the absorption of X-rays by atoms to determine the elemental composition of a sample.
A. Maintains a constant pH
B. Enhances the color of the solution
C. Accelerates the reaction rate
D. Increases the sensitivity of the electrode
A buffer solution in potentiometric titrations maintains a constant pH, preventing significant changes in acidity or alkalinity.
A. Robustness
B. Sensitivity
C. Selectivity
D. Specificity
Robustness in analytical chemistry refers to the ability to produce consistent results under varying conditions.
A. Fluorescence spectroscopy
B. Infrared spectroscopy
C. Ultraviolet spectroscopy
D. Nuclear magnetic resonance
Fluorescence spectroscopy measures the time-dependent decay of excited-state molecules to identify and quantify substances.
A. Ionic charge
B. Molecular weight
C. Density
D. Refractive index
Ion chromatography separates ions based on differences in ionic charge.
A. The lowest concentration that can be reliably measured
B. The point of maximum absorbance in a spectrum
C. The concentration of a standard solution
D. The range of linear response for an instrument
The quantitation limit in analytical chemistry is the lowest concentration that can be reliably measured with acceptable precision and accuracy.
A. Potentiometry
B. Voltammetry
C. Conductometry
D. Coulometry
Potentiometry involves measuring the voltage difference across an electrochemical cell to determine the concentration of an analyte.
A. Measures the intensity of emitted light
B. Records the separation pattern in chromatography
C. Measures the absorbance or emission of light
D. Initiates chemical reactions
A spectrometer in analytical chemistry measures the absorbance or emission of light for analysis.
A. Dynamic light scattering
B. Static light scattering
C. Rayleigh scattering
D. Mie scattering
Dynamic light scattering measures the scattering of light to determine the size and distribution of particles in a sample.
A. Nuclear magnetic resonance (NMR)
B. Electron spin resonance (ESR)
C. Mass spectrometry (MS)
D. Infrared spectroscopy
NMR spectroscopy involves the study of the interaction between a magnetic field and radiofrequency radiation to analyze molecular structures.
A. Conductometry
B. Amperometry
C. Coulometry
D. Voltammetry
Conductometry measures the change in electrical conductivity of a solution during a chemical reaction.
A. Correct for variations in instrumental conditions
B. Enhance sensitivity
C. Provide a reference standard
D. Maintain a constant temperature
Internal calibration standards in analytical chemistry help correct for variations in instrumental conditions.
A. Selectivity
B. Sensitivity
C. Specificity
D. Linearity
Selectivity in analytical chemistry refers to the ability to selectively detect a specific analyte in the presence of other substances.
A. Protects the analytical column from contaminants
B. Enhances the separation efficiency
C. Acts as a reference standard
D. Increases the sample volume
A guard column in chromatography protects the analytical column from contaminants, prolonging its lifespan.
A. Electrophoresis
B. Chromatography
C. Spectroscopy
D. Calorimetry
Electrophoresis measures the movement of charged particles in an electric field to separate and identify ions in a sample.
A. The range over which the instrument provides accurate results
B. The correlation between absorbance and concentration
C. The ability to detect small changes in analyte concentration
D. The straightness of a calibration curve
Linearity in analytical methods refers to the straightness of a calibration curve, indicating a proportional relationship between instrument response and analyte concentration.
A. Gas chromatography-mass spectrometry (GC-MS)
B. High-performance liquid chromatography (HPLC)
C. Ultraviolet-visible spectroscopy (UV-Vis)
D. Infrared spectroscopy
GC-MS is commonly used for the detection and quantification of organic compounds in gas samples.
A. Provides a stable potential against which the analyte electrode can be measured
B. Measures the absorbance of light in a sample
C. Initiates the chemical reaction
D. Enhances the color of the solution
A reference electrode in potentiometric measurements provides a stable potential against which the analyte electrode can be measured.
A. Provides separation based on interactions with sample components
B. Carries the sample through the column
C. Measures the intensity of emitted light
D. Initiates the chemical reaction
The stationary phase in gas chromatography provides separation based on interactions with sample components.
A. X-ray diffraction (XRD)
B. X-ray fluorescence (XRF)
C. X-ray photoelectron spectroscopy (XPS)
D. X-ray absorption spectroscopy
XRD uses X-rays to determine the crystal structure of a sample by analyzing the diffraction pattern.
A. Selectively isolates a specific wavelength of light
B. Amplifies the signal from the detector
C. Initiates the chemical reaction
D. Measures the temperature of the sample
A monochromator in spectroscopy selectively isolates a specific wavelength of light for analysis.
A. X-ray fluorescence (XRF)
B. Mass spectrometry (MS)
C. Nuclear magnetic resonance (NMR)
D. Gas chromatography (GC)
XRF is suitable for analyzing the elemental composition of solid samples.
A. Measures the intensity of emitted light
B. Records the separation pattern in chromatography
C. Measures the absorbance or emission of light
D. Initiates chemical reactions
A detector in gas chromatography records the separation pattern of components.
A. Repeatability
B. Robustness
C. Linearity
D. Sensitivity
Repeatability in analytical chemistry refers to the precision and reproducibility of results obtained from the same sample under identical conditions.
A. The linear relationship between absorbance and concentration
B. The effect of temperature on absorbance
C. The wavelength of maximum absorbance
D. The interaction of light with matter
The Beer-Lambert law in spectrophotometry describes the linear relationship between absorbance and concentration of a sample.